Salt-assisted solution combustion synthesis of NiFe2O4: Effect of salt type

The effects of three types of salt including NaF, KCl, and NaCl on the properties of NiFe₂O₄ nanoparticles using salt-assisted solution combustion synthesis (SSCS) have been investigated. The synthesized powders were evaluated by SEM, TEM, FTIR, XRD, and VSM analysis. Also, the specific surface area (SSA), as well as size distribution and volume of the porosities of NiFe₂O₄ powders were determined by the BET apparatus. The visual observations showed that the intensity and time of combustion synthesis of nanoparticles have been severely influenced by the type of salt. The highest crystallinity was observed in the synthesized powder using NaCl. The SSA has also been correlated completely to the type of salt. The quantities of SSA was achieved about 91.62, 64.88, and 47.22 m²g^-1 for the powders synthesized by KCl, NaCl, and NaF respectively. Although the magnetic hysteresis loops showed the soft ferromagnetic behavior of the NiFe₂O₄ nanoparticles in all conditions, KCl salt could produce the particles with the least coercivity and remanent magnetization. Based on the present study, the salt type is a key parameter in the SSCS process for the preparation of spinel ferrites. Thermodynamic evaluation also showed that the melting point and heat capacity are important parameters for the proper selection of the salt.     

Silicon Mitigates Drought Stress in Wheat (Triticum aestivum L.) Through Improving Photosynthetic Pigments,Biochemical and Yield Characters

Silicon - Feeling prone to stress differs with plant production stage, water scarcity near commencement of grain filling phase has a significant reduced grain yield through fewer endosperm and sink...     

Multi carrier energy systems and energy hubs: Comprehensive review,survey and recommendations

In this paper, the multi carrier energy (MCE) systems are reviewed from different point of views including mathematical models, integrated components and technologies, uncertainty management, planning objectives, environmental pollution, resilience, and robustness. The basic of MCE systems is formed by combination of cooling, heating and power (CCHP). The natural gas and electricity are the main inputs to MCE systems and the cooling, heating, and electricity are the common outputs. The regular energy converters in the MCE systems are combined heat and power (CHP), gas boiler, absorption-electrical chillers, power to gas (P2G) and fuel-cell. The generic energy storages are electrical, heating, cooling, hydrogen, carbon dioxide (CO₂) and hydro systems.     

Hydrogen production by silica membrane reactor during dehydrogenation of methylcyclohexane: CFD analysis

A comprehensive computational fluid dynamic model has been developed using COMSOL Multiphysics 5.4 software to predict the behavior of a membrane reactor in dehydrogenation of methylcyclohexane for hydrogen production. A reliable reaction kinetic of dehydrogenation reaction and a permeation mechanism of hydrogen through silica membrane have been used in computational fluid dynamic modeling. For performance comparison, an equivalent traditional fixed bed reactor without hydrogen removal has been also modeled. After model validation, it has been used to evaluate the operating parameters effect on the performance of both the silica membrane reactor and the equivalent traditional reactor as well. The operating temperature ranged between 473 and 553 K, pressure between 1 and 2.5 bar, sweep factor from ?6.22 to 25 and feed flow rate from 1 to 5 × 10^?6 mol/s. The membrane reactor performed better than the equivalent traditional reactor, achieving as best result complete methylcyclohexane conversion and 96% hydrogen recovery.     

In situ solvent formation microextraction based on a new ionic liquid for green preconcentration of trace amount of Cu (II) ions in water samples

A simple, fast, and effective analytical technique known as in situ solvent formation microextraction was used to preconcentrate/separate trace amounts of Cu(II) ions in water samples prior to determination by flame atomic absorption spectroscopy. In the present method, 6,6′-(1Z,1′Z)(butane-1,4-diylbis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis-3-bromophenol (Schiff base ligand) as the complexing agent and 1-methyl-3-pentylimidazolium bromide (ionic liquid) as an extracting agent were successfully synthesized and characterized by FTIR, C-NMR, and H-NMR spectroscopies. The effects of several analytical parameters on the method were studied and optimized, and the merits of the method, such as LDR (0.2–1000 µg L^?1), LOD (0.12 µg L^?1), RSD (4.1%), and preconcentration factor (70) were evaluated.     

Tunable passively Q-switched thulium doped fluoride fibre (TDFF) laser using reduced graphene oxide-silver (rGO-Ag) as saturable absorber

A tunable, passively Q-switched thulium doped fluoride fibre (TDFF) laser using a reduced-graphene oxide-silver (rGO-Ag) thin film as a saturable absorber (SA) for S band operation is proposed and its efficacy demonstrated. Over a pump power range of 91.4?mW up to 158.6?mW, passively generated Q-switched pulses are observed with repetition rates from 20 to 34.5?kHz and pulse widths from 3.1 to 7.1?µs. The highest pulse energy observed is 101.2?nJ with a signal to noise ratio of ～42?dB. The proposed laser has a tuning range ～52?nm from 1458 to 1510?nm with a tunable bandpass filter (TBPF) introduced into the cavity.     

Industrie 4.0 Readiness: Green Computing in Relation with Key Performance Indicator for a Manufacturing Industry

Mobile Networks and Applications - An effective measure of Key Performance Indicators (KPIs) is of great significance to enhance the capabilities of a decision support system (DSS) of any...